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Albert Wehrer (1952–1953)
(Permanent Representatives to NATO) (List of heads of mission) -
Nicolas Hommel (1953–1959)
(Permanent Representatives to NATO) (List of heads of mission) -
Paul Reuter (1959–1967)
(Permanent Representatives to NATO) (List of heads of mission) -
Lambert Schaus (1967–1973)
(Permanent Representatives to NATO) (List of heads of mission) -
Marcel Fischbach (1973–1977)
(Permanent Representatives to NATO) (List of heads of mission) -
Pierre Wurth (1977–1984)
(Permanent Representatives to NATO) (List of heads of mission) -
Jean Wagner (1984–1986)
(Permanent Representatives to NATO) (List of heads of mission) -
Guy de Muyser (1986–1991)
(Permanent Representatives to NATO) (List of heads of mission) -
Thierry Stoll (1991–1993)
(Permanent Representatives to NATO) (List of heads of mission) -
Paul Schuller (1993–1998)
(Permanent Representatives to NATO) (List of heads of mission) -
Jean-Jacques Kasel (1998–2003)
(Permanent Representatives to NATO) (List of heads of mission) -
Joseph Weyland (2003–2005)
(Permanent Representatives to NATO) (List of heads of mission) -
Alphonse Berns (2005–2011)
(Permanent Representatives to NATO) (List of heads of mission) -
Jean-Jacques Welfring (2011–2016)
(Permanent Representatives to NATO) (List of heads of mission) -
Arlette Conzemius (September 2016–date)
(Permanent Representatives to NATO) (List of heads of mission)
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